I was being the “expert” on a school plant stall recently when I was questioned about how to change the colour of hydrangeas, specifically how to make pink hydrangeas blue and if nails and steel wool added to the soil would work. Coming from a science background I have to forget the litmus colour test where blue turning red indicates acid and red turning blue indicates alkaline. The hydrangea indicator is the reverse of litmus. A pink hydrangea indicates alkaline soil and a blue hydrangea indicates acid soil. Purple indicates a neutral solution with litmus and a neutral soil with hydrangeas. White hydrangeas are not affected by soil pH although I have noticed a thin blue or pink margin around some.
I have done a bit of follow up research and find that aluminium ions are the key for the hydrangea pH indicator. In acidic soil aluminium is available and will change the pink to blue. In alkaline soils the aluminium becomes immobile as aluminium hydroxide and the hydrangea is pink.
The mountain soils are generally acid and we would assume therefore that our hydrangeas would be blue. We actually have a few neutral purple hydrangeas and many that are pink. A soil test in the vicinity of the pink plants revealed pH6.5. This is a bit close to neutral for a good blue as aluminium begins to become unavailable above pH5.5. The plants that are pink may have their roots into the lime mortar of the rock walls, lime may have been added to the garden in the past or there may be insufficient aluminium in this patch of soil. Achieving a pink hydrangea is just a matter of adding lime but turning a pink hydrangea blue is more difficult. The usual method is to add an acidic aluminium complex such as aluminium sulphate. This will kill the plant at high concentrations and kills the microorganisms in the soil so for us is not an option. Rusty nails, coffee grounds, citrus peelings, pine needles, pine bark and organic matter generally will all have a slightly acidifying effect. As there are purple plants in the bed there must be some aluminium present. The bed in the photos was renovated earlier in 2015, see Mop Head Hydrangea Bed Renovation, and has flowered very well considering the severe treatment it received. We will stick with our present colour combination. We are adding organic matter in the form of compost but I think a colour shift is a long way off.